S8 · Grade Boundaries by Medium

Boundary for Same Medium (904L/254SMO Media and Boundary List)

List out the media, grades, and boundary conditions related to "Boundary for Same Medium": 5 typical components/processes, including recommended grades, specifications, failure reasons, and standards.

Steel coils, sheets, and fastener flanges in stock
Metal products: cold-rolled coils, sheets, fasteners, and flanges (schematic; actual selection based on media, temperature, and drawings)

List of selected parts for five locations

Location / PartRecommended designationSpecification / ThicknessSurfaceMain Failure ModesReference Standards
Sulfuric Acid H₂SO₄ 20–40%904L/254SMO2507 (over 50mm/a at 40%); 316L/317L severely corroded2507 corrodes over 50mm/a in 40% H₂SO₄Sulfuric Acid is not a strength of duplex stainless steel; high molybdenum austenitic/superalloy required for medium to high concentrationsASTM A240; Corrosion charts
Hydrochloric Acid HCl 20%C276/C22316L perforates in about 3 days; 904L not suitable for long-term use in hydrochloric acidC276 typically <0.1mm/a in HCl; 10% H₂SO₄, 80°C <0.1mm/aHydrochloric Acid requires nickel-based alloys; high molybdenum does not equal resistance to hydrochloric acidASTM B575; Haynes data
Phosphoric Acid H₃PO₄ (pure)904L/316L/317L (mild)444/304 inadequate in hot concentrated phosphoric acidCorrosion curves: 444→304→316/317→904L904L is a common upgrade endpoint in phosphoric acid plants; further evaluate 254SMO when Cl⁻/F⁻ are present.ASTM A240; corrosion maps
High chloride seawater / RO concentrate water2507/254SMO316L months pitting / SCC; 2205 narrow boundary at high temperature and high chlorideConcentrated saltwater Cl⁻ 60,000–80,000 ppm; 2507 CPT > 50°C, PREN 41–432507 is an economical high-corrosion-resistant choice for seawater desalination at high pressure; select 254SMO/6Mo when temperature and Cl⁻ exceed.ASTM A240/A789/A182
Wet flue gas desulfurization acidic wash solution2205/2507/254NM/AL-6XN304L/316L significant corrosion; rapid perforation at wet-dry interfaceCorrosion rates: 2507 < 2205 < TA2 < 316LBy component classification: spray/scrubbing 2205/2507; inlet flue gas/tower lining 254NM/904L/AL-6XNASTM A240;DL/T 5196
See below forstandard configuration.The same part can be replaced with 304, 316L, or 2205 depending on the medium, temperature, and welding method —— specify usage conditions to save time.

Key material considerations

  • The most common grades in this industry are 904L (2), 254SMO (2), and 2507 (2) —— parentheses indicate affected areas, useful for quoting and inventorying.
  • Chloride ions and salts are the most common corrosion sources (pitting, fretting corrosion) (3/5 hits).
  • Acid Media 316L Only Starts Here, Up the Concentration and Temperature to See 904L / Dual Phase (3/5 Hits).

Common Issues

Which Stainless Steel is Used Most in the Same Medium: Sulfuric Acid/Polyphosphoric Acid/Sulfuric Acid/Low Chloride?
Top 5 Parts by Occurrence: 904L (2), 254SMO (2), 2507 (2). Specific to a part still depends on the medium and temperature, e.g., stainless steel countertops require switching from 304 to 316L when exposed to saltwater.
Most Common Issues?
Typical Failure Modes: Wet FGD Acid Wash Solution. By Part Classification: Spray/Dehumidification - 2205/2507; Inlet Chimney/Tower Liner - 254NM/904L/AL-6XN; Recommended Grades 2205/2507/254NM/AL-6XN, Specified Corrosion Resistance. Dry/Wet Interface Penetration Fast. For these conditions, it's recommended to specify medium concentration, temperature, and cleaning method during the design phase.

Related Materials and Adjacent Industries

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